Solid-solid reactions of Basic Copper Carbonate with ci […]
Solid-solid reactions of Basic Copper Carbonate with cinnamic, succinic and adipic acids give the corresponding copper(II) carboxylate chelates with the elimination of carbon dioxide and water. Products were characterized by spectral and magnetic studies.
The kinetic measurements were made at various temperatures for a fixed particle size of the reactants under constant compression. The reactions are diffusion controlled with activation energies of 19.9, 8.8 and 15.9 kJ mol? for the formation of Cu(II) cinnamate, Cu(II) succinate and Cu(II) adipate, respectively.
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